Borate bromide

Mixed anion compounds

The borate bromides are mixed anion compounds that contain borate and bromide anions. They are in the borate halide family of compounds which also includes borate fluorides, borate chlorides, and borate iodides.

List

name chem mw crystal system space group unit cell Å volume density comment references
Li3B8O13Br 395.21 orthorhombic Pca21 a 17.3967(5)Å b 9.4077(3)Å c 6.6750 1092.45 2.403 birefringence 0.088@1064 nm [1]
Na3B4O7Br hexagonal P6522 a = 8.146 c = 20.24 1163.1 2.605 [2]
Na11B21O36Br2 1215.72 monoclinic C2/c a=15.722 b=8.951 c=24.087 β=100.728 Z=4 3330.3 2.425 [3]
KBOB K3B6O10Br 422.07 trigonal R3m a=10.1153 c=8.8592 Z=3 785.02 2.678 colourless [4]
K9[B4O5(OH)4]3(CO3)Br·7H2O 1191.75 hexagonal P6_2c a=11243 c=17.132 Z=2 1875 2.11 band gap 5.65 eV [5]
Zn2BO3Br·H2O 287.48 orthorhombic P212121 a=4.962 b=8.484 c=14.644 Z=4 616.5 3.097 NLO 0.6x KDP [6]
KZn2BO3Br2 345.92 trigonal R32 a=4.9611 c=27.221 Z=3 580.2 2.970 white [7]
RbZn2BO3Br2 388.47 trigonal R32 a=4.9618 c=28.199 Z=3 601.2 3.219 white [7]
Ag4B4O7Br2 746.52 hexagonal P6122 a=8.8291 c=44.7416 Z=12 3020.5 4.92 [8]
Sn2B5O9Br 515.34 orthorhombic Pnn2 a = 11.398 b = 11.446 c = 6.553 Z=4 854.9 4.004 birefringence=0.439 at 546 nm; SHG 4.8x; white [9]
NaBa4(GaB4O9)2Br3 1326.00 tetragonal P42nm a=12.33 c=6.91 Z=2 1053 4.18 NLO 1.1x KDP [10]
La[B5O8(OH)(H2O)2Br] 448.87 monoclinic P21/n a=6.520 b=15.213 c=10.704 β=90.017 Z=4 1061.6 2.808 colourless [11]
LaBOBr La[B7O10(OH)3(H2O)Br] 518.49 monoclinic P21/n a=7.944 b=15.105 c=9.836 β=90 Z=4 1180.3 2.918 [12]
Ce[B5O8(OH)(H2O)2Br] 450.08 monoclinic P21/n a=6.495 b=15.159 c=10.670 β=90.048 Z=4 1050.6 2.846 colourless [11]
CeBOBr Ce[B6O9(OH)2(H2O)2Br]·0.5H2O 500.89 monoclinic P21/n a=8.1507 b=14.874 c=9.867 β=90.085 Z=4 1196.3 2.781 [12]
PrBOBr Pr[B6O9(OH)2(H2O)2Br]·0.5H2O 501.68 monoclinic P21/n a=8.1346 b=14.819 c=9.847 β=90.153 Z=4 1187.0 2.807 green [12]
Pr[B5O8(OH)(H2O)2Br] 450.87 monoclinic P21/n a=6.4910 b=15.143 c=10.664 β=90.0440 Z=4 1048.2 2.857 [11]
NdBOBr Nd2[B12O17.5(OH)5(H2O)4Br1.5]Br0.5·H2O 1018.02 orthorhombic Fdd2 a=30.6641 b=19.7946 c=16.0737 Z=16 9757.3 2.772 purple [12]
Nd4[B18O25(OH)13Br3] 1619.27 monoclinic P2/c a=10.544 b=6.451 c=23.485 β=97.754 Z=2 1583 3.397 purple [11]
SmBOBr Sm4[B18O25(OH)13Br3] 1643.71 monoclinic P21/n a=10.508 b=6.427 c=23.408 β=97.585 Z=2 1567 3.484 [12]
Ba2BO3Br P-3m1 a = 5.516, c = 11.019, and Z = 2 [13]
Ba3BO3Br3 triclinic P-1 a = 9.280, b = 9.349 c = 13.025, α = 92.71°, β = 98.29°, γ = 116.20° and Z = 4 [13]
Ba7(BO3)3SiO4Br orthorhombic P63mc [14]
Ba7(BO3)3GeO4Br 1354.31 orthorhombic Pbam a=20.381 b=7.477 c=11.175 Z=4 1702.9 5.283 [14]
Pb2Ba3(BO3)3Br 1082.74 orthorhombic C2221 a=10.538 b=14.2878 c=8.107 Z=4 1220.7 5.891 NLO 3.1×KDP; colourless [15]

References

  1. ^ Hu, Mei; Tuerhong, Nuerbiye; Chen, Zhaohui; Jing, Qun; Lee, Ming-Hsien (2023-02-16). "Li 3 B 8 O 13 X (X = Cl and Br): Two New Noncentrosymmetric Crystals with Large Birefringence Induced by BO 3 Units". Inorganic Chemistry. 62 (8): 3609–3615. doi:10.1021/acs.inorgchem.2c04376. ISSN 0020-1669. PMID 36795025. S2CID 256899976.
  2. ^ Bai, Chunyan; Han, Shujuan; Pan, Shilie; Zhang, Bingbing; Yang, Yun; Li, Lin; Yang, Zhihua (2015). "Na 3 B 4 O 7 X (X = Cl, Br): two new borate halides with a 1D Na-X (X = Cl, Br) chain formed by the face-sharing XNa 6 octahedra". RSC Advances. 5 (16): 12416–12422. Bibcode:2015RSCAd...512416B. doi:10.1039/C4RA16639F. ISSN 2046-2069.
  3. ^ Dong, Xiaoyu; Wu, Hongping; Shi, Yunjing; Yu, Hongwei; Yang, Zhihua; Zhang, Bingbing; Chen, Zhaohui; Yang, Yun; Huang, Zhenjun; Pan, Shilie; Zhou, Zhongxiang (2013-06-03). "Na 11 B 21 O 36 X 2 (X=Cl, Br): Halogen Sodium Borates with a New Graphene-Like Borate Double Layer". Chemistry - A European Journal. 19 (23): 7338–7341. doi:10.1002/chem.201300902. PMID 23630069.
  4. ^ Zhang, Min; Su, Xin; Pan, Shilie; Wang, Zheng; Zhang, Hui; Yang, Zhihua; Zhang, Bingbing; Dong, Lingyun; Wang, Ying; Zhang, Fangfang; Yang, Yun (2014-06-05). "Linear and Nonlinear Optical Properties of K 3 B 6 O 10 Br Single Crystal: Experiment and Calculation". The Journal of Physical Chemistry C. 118 (22): 11849–11856. doi:10.1021/jp500858q. ISSN 1932-7447.
  5. ^ Zhang, Xueyan; Wu, Hongping; Cheng, Shichao; Han, Guopeng; Yang, Zhihua; Pan, Shilie (2019-05-20). "K 9 [B 4 O 5 (OH) 4 ] 3 (CO 3 )X·7H 2 O (X = Cl, Br): Syntheses, Characterizations, and Theoretical Studies of Noncentrosymmetric Halogen Borate–Carbonates with Short UV Cutoff Edges". Inorganic Chemistry. 58 (10): 6974–6982. doi:10.1021/acs.inorgchem.9b00593. ISSN 0020-1669. PMID 31042371. S2CID 143422681.
  6. ^ Song, Yunxia; Yang, Guangsai; Gong, Pifu; Luo, Min; Lin, Zheshuai; Ye, Ning (2020-06-01). "Hydrogen-Bond-Assisted Reinforcement of Interlayer Connections in Zn 2 BO 3 X·H 2 O (X = Cl, Br): Two UV Nonlinear Optical Crystals with KBBF-Type Structure". Inorganic Chemistry. 59 (11): 7789–7794. doi:10.1021/acs.inorgchem.0c00874. ISSN 0020-1669. PMID 32401026. S2CID 218618490.
  7. ^ a b Yang, Guangsai; Gong, Pifu; Lin, Zheshuai; Ye, Ning (2016-12-27). "AZn 2 BO 3 X 2 (A = K, Rb, NH 4 ; X = Cl, Br): New Members of KBBF Family Exhibiting Large SHG Response and the Enhancement of Layer Interaction by Modified Structures". Chemistry of Materials. 28 (24): 9122–9131. doi:10.1021/acs.chemmater.6b04272. ISSN 0897-4756.
  8. ^ Volkov, Sergey N.; Charkin, Dmitri O.; Arsent’ev, Maxim Yu.; Povolotskiy, Alexey V.; Stefanovich, Sergey Yu.; Ugolkov, Valery L.; Krzhizhanovskaya, Maria G.; Shilovskikh, Vladimir V.; Bubnova, Rimma S. (2020-03-02). "Bridging the Salt-Inclusion and Open-Framework Structures: The Case of Acentric Ag 4 B 4 O 7 X 2 (X = Br, I) Borate Halides". Inorganic Chemistry. 59 (5): 2655–2658. doi:10.1021/acs.inorgchem.0c00306. ISSN 0020-1669. PMID 32049501. S2CID 211101969.
  9. ^ Guo, Jingyu; Cheng, Shichao; Han, Shujuan; Yang, Zhihua; Pan, Shilie (March 2021). "Sn 2 B 5 O 9 Br as an Outstanding Bifunctional Material with Strong Second-Harmonic Generation Effect and Large Birefringence". Advanced Optical Materials. 9 (5): 2001734. doi:10.1002/adom.202001734. ISSN 2195-1071. S2CID 230528677.
  10. ^ Wen, Ming; Su, Xin; Wu, Hongping; Lu, Juanjuan; Yang, Zhihua; Pan, Shilie (2016-03-24). "NaBa 4 (GaB 4 O 9 ) 2 X 3 (X = Cl, Br) with NLO-Active GaO 4 Tetrahedral Unit: Experimental and ab Initio Studies". The Journal of Physical Chemistry C. 120 (11): 6190–6197. doi:10.1021/acs.jpcc.6b00265. ISSN 1932-7447.
  11. ^ a b c d Polinski, Matthew J.; Wang, Shuao; Cross, Justin N.; Alekseev, Evgeny V.; Depmeier, Wulf; Albrecht-Schmitt, Thomas E. (2012-07-16). "Effects of Large Halides on the Structures of Lanthanide(III) and Plutonium(III) Borates". Inorganic Chemistry. 51 (14): 7859–7866. doi:10.1021/ic3009317. ISSN 0020-1669. PMID 22734798.
  12. ^ a b c d e Polinski, Matthew J.; Alekseev, Evgeny V.; Darling, Victoria R.; Cross, Justin N.; Depmeier, Wulf; Albrecht-Schmitt, Thomas E. (2013-02-18). "A New Family of Lanthanide Borate Halides with Unusual Coordination and a New Neodymium-Containing Cationic Framework". Inorganic Chemistry. 52 (4): 1965–1975. doi:10.1021/ic302309z. ISSN 0020-1669. PMID 23360290.
  13. ^ a b Zhao, Jing; Li, R.K. (October 2013). "Two new barium borate bromides: Ba2BO3Br and Ba3BO3Br3". Solid State Sciences. 24: 54–57. Bibcode:2013SSSci..24...54Z. doi:10.1016/j.solidstatesciences.2013.07.009.
  14. ^ a b Wen, Ming; Lian, Zhipeng; Wu, Hongping; Su, Xin; Yan, Qingfeng; Lu, Juanjuan; Yang, Zhihua; Pan, Shilie (2015). "Ba 7 (BO 3 ) 3 GeO 4 X (X = Cl, Br): borogermanate halides with rigid GeO 4 tetrahedra and flexible XBa 6 octahedra". RSC Advances. 5 (66): 53448–53454. Bibcode:2015RSCAd...553448W. doi:10.1039/C5RA07450A. ISSN 2046-2069.
  15. ^ Jing, Qun; Dong, Xiaoyu; Yang, Zhihua; Pan, Shilie (2015). "Synthesis and optical properties of the first lead borate bromide with isolated BO 3 groups: Pb 2 Ba 3 (BO 3 ) 3 Br". Dalton Transactions. 44 (38): 16818–16823. doi:10.1039/C5DT02652K. ISSN 1477-9226. PMID 26347088.
  • v
  • t
  • e
Borates
H3BO3 He
Li2B4O7 Be B +(CO3)
+(C2O4) 		(NH4)3BO3
+NO3 		O +F Ne
Na2[B4O5(OH)4]·8H2O
NaBO2
NaBO3
Na3BO3
Na2B8O13 		Mg3(BO3)2 AlBO3 Si -PO4
+PO4 		+S
-SO4
+SO4 		+Cl Ar
K2B4O7•4H2O
KB5O8•4H2O 		Ca3(BO3)2 ScBO3 TiBO3 -VO4 Cr Mn3(BO3)2 Fe3(BO3)2
FeBO3
FeB(OH)4 		Co3(BO3)2 Ni3(BO3)2 Cu3(BO3)2 Znx(BO3)x GaBO3
-GaO4 		-GeO4 -AsO4 -SeO4
-SeO3
+Se 		+Br Kr
Rb3BO3
RbB11O16(OH)2
Rb[B5O6(OH)4]•2H2O 		Sr3(BO3)2 YBO3 ZrB2O5 Nb Mo Tc Ru Rh Pd Ag3BO3 Cd3(BO3)2 InBO3 Sn -SbBO4 -TeO4
-TeO3 		+I Xe
Cs3BO3
CsB5O8•4H2O 		BaB2O4 * Lu3B5O12 HfB2O5 Ta W Re Os Ir Pt Au Hg Tl3BO3 Pb3(BO3)2 BiBO3 Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* LaB3O6 CeB3O6 Pr4B10O21 NdBO3 Pm Sm Eu Gd Tb Dy4B6O15
Dy2B4O9 		Ho4B6O15
Ho2B4O9 		ErBO3 Tm3B5O12 Yb3B5O12
** Ac Th3(BO3)4 Pa U(BO3)2 Np Pu Am Cm Bk Cf[B6O8(OH)5] Es Fm Md No
  • v
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  • e
Salts and covalent derivatives of the bromide ion
HBr He
LiBr BeBr2 BBr3
+BO3 		CBr4
+C 		NBr3
BrN3
NH4Br
NOBr
+N 		Br2O
BrO2
Br2O3
Br2O5 		BrF
BrF3
BrF5 		Ne
NaBr MgBr2 AlBr
AlBr3 		SiBr4 PBr3
PBr5
PBr7
+P 		S2Br2
SBr2 		BrCl Ar
KBr CaBr2
 ScBr3 TiBr2
TiBr3
TiBr4 		VBr2
VBr3 		CrBr2
CrBr3 		MnBr2 FeBr2
FeBr3 		CoBr2 NiBr2
NiBr42− 		CuBr
CuBr2 		ZnBr2 GaBr3 GeBr2
GeBr4 		AsBr3
+As
+AsO3 		SeBr2
SeBr4 		Br2 Kr
RbBr SrBr2 YBr3 ZrBr3
ZrBr4 		NbBr5 MoBr2
MoBr3
MoBr4 		TcBr4 RuBr3 RhBr3 PdBr2 AgBr CdBr2 InBr
InBr3 		SnBr2
SnBr4 		SbBr3
+Sb
-Sb 		Te2Br
TeBr4
+Te 		IBr
IBr3 		XeBr2
CsBr BaBr2 * LuBr3 HfBr4 TaBr5 WBr5
WBr6 		ReBr3 OsBr3
OsBr4 		IrBr3
IrBr
4 		PtBr2
PtBr4 		AuBr
AuBr3 		Hg2Br2
HgBr2 		TlBr PbBr2 BiBr3 PoBr2
PoBr4 		AtBr Rn
FrBr RaBr2 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* LaBr3 CeBr3 PrBr3 NdBr2
NdBr3 		PmBr3 SmBr2
SmBr3 		EuBr2
EuBr3 		GdBr3 TbBr3 DyBr3 HoBr3 ErBr3 TmBr2
TmBr3 		YbBr2
YbBr3
** AcBr3 ThBr4 PaBr4
PaBr5 		UBr4
UBr5 		NpBr3
NpBr4 		PuBr3 AmBr2
AmBr3 		CmBr3 BkBr3 CfBr3 EsBr2
EsBr3 		Fm Md No